Additional scenes of Rogue and Minevra were added in anime however was not present in manga.
The angle at which Larcade stabs Sting with his weapon is different than in mange since Larcade actually stabs Sting in his shoulders however the angle of aim done in the anime allowed Sting to grab/doge the attack.
After using Territory Magic to switch Yukino and Rogue's posistion, an additional scene was added in the anime where Yukino was sent to Minerva and she starts nibbling on her.