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Natsu Dragneel vs. Zeref Dragneel is a fight fought between the Mage of Fairy Tail, the Fire Dragon Slayer Natsu Dragneel and the Black Mage, also known as the Emperor Spriggan, Zeref Dragneel.

Prologue
Having defended against the first wave of the Alvarez Empire's assault, the Fairy Tail members gather at the guild hall to discuss the situation, facing enemies from every direction. Even though Mavis originally disagrees with getting others involved, she eventually accepts the idea of Mages outside of Fairy Tail helping. While Lucy tries to question the now-captured Brandish, the western army of the Alvarez Empire lead by Zeref receives the news of Brandish and Ajeel's defeats. Upon hearing this, Zeref smiles, noting that otherwise, the things would be boring, however, he also points out that Fairy Tail not killing their enemies is their weakness. Meanwhile, the news from the east arrive and Fairy Tail Mages learn that all of Bosco's guilds have been defeated. However, the Mages of Fiore also move out, with Sabertooth and Blue Pegasus going to intercept the army coming from the north, Mermaid Heel and Lamia Scale heading out to liberate Hargeon Town in the south. Several Fairy Tail Mages are sent to help those out, however, they soon notice that Natsu, who is supposed to join one of those groups, is nowhere to be found. After it is revealed that Four Gods of Ishgar will face the greatest threat coming from the east, Natsu's location finally becomes known and everyone witnesses the Fire Dragon Slayer flying towards their main enemy, Zeref.

This causes a discord between Erza and Gray, with the two disagreeing on whether to trust Natsu and his reckless action. However, eventually, the Mages agree to follow the original plan and leave Zeref to Natsu. Meanwhile, Natsu makes the first contact with the enemy forces, charging straight into them with an intention to make Zeref appear. He takes out a huge number of soldiers, using his Magic for both offense and defense as the Alvarez soldiers fire back with their ranged weapons. Even though it seems like Natsu gets overwhelmed by these attacks, he quickly replies with Fire Dragon King's Roar, eliminating almost thousand soldiers in total by that point. Finally, Zeref makes an appearance and Natsu notes that he thought it'd take more than that to make the big guy come out. As Zeref replies that he wanted to see Natsu as soon as possible, the Fire Dragon Slayer gets ready, removing the bandage from his right arm.